CaO-based CO2 sorbents effectively stabilized by metal oxides

We report a Pechini method to synthesize cyclically stable, CaO-based CO2 sorbents with a high CO2 uptake capacity.

The sorbents synthesized feature compositional homogeneity in combination with a nanostructured and highly porous morphology. When Al2O3 and Y2O3 were introduced together as stabilizers, a synergistic effect was observed whereby the bimetal oxide-stabilized sorbent featured an improved performance as compared to the sorbent stabilized by the same quantity of the single metal oxides of Al2O3 or Y2O3. The formation of a YAG phase between Al2O3 and Y2O3 leads to a sorbent with a higher fraction of CO2-capture-active CaO, since some Al2O3 reacted with Y2O3 and not with CaO.

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