CaO-based CO2 sorbents effectively stabilized by metal oxides
We report a Pechini method to synthesize cyclically stable, CaO-based CO2 sorbents with a high CO2 uptake capacity.
The sorbents synthesized feature compositional homogeneity in combination with a nanostructured and highly porous morphology. When Al2O3 and Y2O3 were introduced together as stabilizers, a synergistic effect was observed whereby the bimetal oxide-stabilized sorbent featured an improved performance as compared to the sorbent stabilized by the same quantity of the single metal oxides of Al2O3 or Y2O3. The formation of a YAG phase between Al2O3 and Y2O3 leads to a sorbent with a higher fraction of CO2-capture-active CaO, since some Al2O3 reacted with Y2O3 and not with CaO.
external page http://onlinelibrary.wiley.com/doi/10.1002/cphc.201700695/full
DOI: 10.1002/cphc.201700695